![iron oxidation titation lab backcalculation iron oxidation titation lab backcalculation](https://d20ohkaloyme4g.cloudfront.net/img/document_thumbnails/e87e889201b2184f61278eb229697c50/thumb_300_388.png)
The change in titration curve depends also on the concentration of sample and titrant solution analogously to other titration types.
![iron oxidation titation lab backcalculation iron oxidation titation lab backcalculation](https://media.cheggcdn.com/media/ed9/ed9c9425-6ad5-4c7e-b28a-18a26a0cf0fa/phpvmlzd5.png)
Titration with visual detection is possible for a complex of stability constant higher than 10 7. The change of the pMe in the end point region increases with the increase of the stability constant of the formed complex. Thus, to prevent a pH change during the titration, the solution must be adequately buffered.Ī titration curve in complexometric titrations shows relationship between pMe and the titrant volume. The reaction of metal ions with EDTA (Eq. Metals forming stronger complexes can be titrated at lower pH values, at which the weaker complexing metals do not react, thus selective titration of Fe 3+ or Bi 3+ can be carried out in the presence of Mg 2+ and Ca 2+ or Pb 2+, respectively at pH 1–2.
![iron oxidation titation lab backcalculation iron oxidation titation lab backcalculation](https://s3.studylib.net/store/data/008506097_1-7f602c9da47bf354f76e9cfdba340df8-300x300.png)
1 Generally metals forming weaker complexes require less acidic (i.e., higher pH) conditions for complex formation. Where “square brackets” denote concentrations (or better, activities).